THE OLIGOMERIZATION OF LOWER OLEFINS BY CATALYSTS DERIVED FROM NI(SACSAC)(PBU3)CL

被引：7

作者：

BROWN, SJ

MASTERS, AF

VENDER, M

SACHINIDIS, JI

TREGLOAN, PA

机构：

[1] UNIV SYDNEY,DEPT INORGAN CHEM,SYDNEY,NSW 2006,AUSTRALIA

[2] UNIV MELBOURNE,DEPT INORGAN CHEM,PARKVILLE,VIC 3052,AUSTRALIA

来源：

POLYHEDRON | 1990年 / 9卷 / 23期

关键词：

D O I：

10.1016/S0277-5387(00)84184-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The dimerization of butenes by a catalyst system derived from (pentane-2,4-dithionato) chlorotri-n-butylphosphinenickel(II) and diethylaluminium chloride in chlorobenzene has been investigated. The data are consistent with the presence of two catalytic species in solution. The concentrations of the catalysts appear to decrease with time, at a rate which is first-order in catalyst concentration, and the initial oligomerization rate appears to be second-order in olefin concentration. © 1990.

引用

页码：2809 / 2814

页数：6

共 22 条

[11] SULFUR CHELATES .33. PREPARATION, CHARACTERIZATION AND X-RAY STRUCTURE DETERMINATION OF (CHLORO)(PENTANE-2,4-DITHIONATO)(TRIETHYLPHOSPHINE)NICKEL(II), NI(SACSAC)(PET3)CL, AN ASYMMETRIC COMPLEX WHICH DISPLAYS FLUXIONAL BEHAVIOR IN SOLUTION ON THE NMR TIME SCALE [J].

FACKLER, JP ;

MASTERS, AF .

INORGANICA CHIMICA ACTA-ARTICLES, 1980, 39 (01) :111-118

[12]

FREITAS ER, 1979, CHEM ENG PROG, V75, P73

[13]

Hobson GD, 1973, MODERN PETROLEUM TEC, V4th

[14]

Jolly P.W., 1975, ORGANIC CHEM NICKEL, V2

[15]

JOLLY PW, 1982, COMPREHENSIVE ORGANO, V8, P615

[16]

KEIM W, 1982, COMPREHENSIVE ORGANO, V8, P371

[17]

Lefebvre G., 1970, ASPECTS HOMOGENEOUS, V1, P107

[18]

MASTERS AF, 1985, Patent No. 4533651

[19] LOW PRESSURE OLIGOMERIZATION OF MONO-OLEFINS WITH SOLUBLE NICKEL-ALUMINUM BIMETAL CATALYSTS .2. REACTION KINETICS OF PROPENE DIMERIZATION [J].

ONSAGER, OT ;

WANG, H ;

BLINDHEI.U .

HELVETICA CHIMICA ACTA, 1969, 52 (01) :196-&

[20]

ONSAGER OT, 1985, CHEM METAL CARBON BO, V3, P205

← 1 2 3 →