ASYMMETRIC MULTIPOINT CONTROL BY PALLADIUM-CATALYZED DIASTEREOSELECTIVE TANDEM CARBON-CARBON BOND FORMATION

被引：28

作者：

TORII, S

OKUMOTO, H

KOTANI, T

NAKAYASU, S

OZAKI, H

机构：

[1] Department of Applied Chemistry, Faculty of Engineering, Okayama University, Naka, Okayama, 700, Tsushima

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 24期

关键词：

DIASTEREODIFFERENTIATION; PALLADIUM-CATALYSIS; NORBORNENE; ACETYLENE; ALKENYL IODIDE;

D O I：

10.1016/S0040-4039(00)92674-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Palladium-catalyzed diastereo-differentiative tandem connection of cis-alkenyl iodide, cyclic fragment, and terminal acetylene was executed. The discrimination of the diastereotopic face and olefinic carbons of norbornene was achieved with accompanying isomerization of the cis-geometry of the olefin to trans in good yields.

引用

收藏

页码：3503 / 3506

页数：4

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