ENANTIOSELECTIVE CATALYTIC BORANE REDUCTIONS OF ACHIRAL KETONES - SYNTHESIS AND APPLICATION OF NEW CATALYSTS PREPARED FROM (S)-TERT-LEUCINE AND (S)-AZETIDINECARBOXYLIC ACID

被引：38

作者：

BEHNEN, W ^{[1
]}

DAUELSBERG, C ^{[1
]}

WALLBAUM, S ^{[1
]}

MARTENS, J ^{[1
]}

机构：

[1] UNIV OLDENBURG,FACHBEREICH CHEM,AMMERLANDER HEERSTR 114-118,W-2900 OLDENBURG,GERMANY

来源：

SYNTHETIC COMMUNICATIONS | 1992年 / 22卷 / 15期

关键词：

D O I：

10.1080/00397919208019066

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Enantiocontrolled reduction of prochiral ketones with borane in the presence of homochiral amino alcohols 1 - 3 as enantioselective catalysts afforded the corresponding secondary alcohols in moderate to high (69 to >99 %) optical yields.

引用

页码：2143 / 2153

页数：11

共 36 条

[31] SEYDENPENNE J, 1991, REDUCTIONS ALUMINO B
[32] ENANTIOSELECTIVE HYDROGENATION OF ACETOPHENONE IN THE PRESENCE OF S-PROLINE
TUNGLER, A
TARNAI, T
MATHE, T
PETRO, J
[J]. JOURNAL OF MOLECULAR CATALYSIS, 1991, 67 (02): : 277 - 282
[33] ENANTIOSELECTIVE CATALYTIC REDUCTIONS OF KETONES - SYNTHESIS AND APPLICATION OF A NEW STRUCTURALLY RIGID BICYCLIC CATALYST
WALLBAUM, S
MARTENS, J
[J]. TETRAHEDRON-ASYMMETRY, 1991, 2 (11) : 1093 - 1096
[34] SYNTHESIS OF OPTICALLY-ACTIVE 1,3,2-OXAZAPHOSPHOLIDINE 2-SULFIDES AND 1,3,2-BENZODIOXAPHOSPHORIN 2-SULFIDES
WU, SY
HIRASHIMA, A
KUWANO, E
ETO, M
[J]. AGRICULTURAL AND BIOLOGICAL CHEMISTRY, 1987, 51 (02): : 537 - 547
[35] YAMAGUCHI AS, 1978, J ORG CHEM, V38, P1870
[36] YOUN K, 1989, TETRAHEDRON LETT, V29, P4453

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