SYNTHESIS AND REACTIVITY OF (TRICARBONYL)-(ETA-5-2-METHYLPENTADIENYL)IRON(+ 1) CATION

被引：28

作者：

DONALDSON, WA

机构：

[1] Department of Chemistry, Marquette University, Milwaukee

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1990年 / 395卷 / 02期

基金：

美国国家科学基金会; 美国国家卫生研究院;

关键词：

D O I：

10.1016/0022-328X(90)85276-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The (tricarbonyl)(η5-2-methylpentadienyl)iron(+1) cation was prepared by the protonation of (tricarbonyl)(4-methyl-2,4-pentadienol)iron. Reaction of the cation with H2O, allyl-TMS, NaBH3CN, PPh3, malonate and 3-furyl cuprate gave (η4-1,3-diene)Fe(CO)3 complexes. The regioselectivity for the nucleophilic attack appears to be sterically controlled. © 1990.

引用

页码：187 / 193

页数：7

共 25 条

[1] REACTION OF PENTADIENYLIRON TRICARBONYL CATIONS WITH HYDRIDE DONORS [J].

BAYOUD, RS ;

BIEHL, ER ;

REEVES, PC .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1979, 174 (03) :297-303

[2] REACTIONS OF UNSYMMETRICALLY SUBSTITUTED PENTADIENYLIRON TRICARBONYL CATIONS WITH WATER [J].

BAYOUD, RS ;

BIEHL, ER ;

REEVES, PC .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1978, 150 (01) :75-83

[3] REGIOSELECTIVITY OF NUCLEOPHILIC ADDITIONS TO TRICARBONYL[ETA-5-2-METHYL-2,4-CYCLOHEXADIEN-1-YL]IRON(1+)PF6(-) - TEMPERATURE-DEPENDENCE OF HYDRIDE REDUCTIONS [J].

BIRCH, AJ ;

STEPHENSON, GR .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1981, 218 (01) :91-104

[4]

BIRCH AJ, 1976, J CHEM SOC PERK T 1, P954, DOI 10.1039/p19760000954

[5] ELECTROPHILIC SUBSTITUTION OF 1,3-DIMETHOXYBENZENE BY PENTADIENYLTRICARBONYLIRON CATIONS [J].

BONNER, TG ;

HOLDER, KA ;

POWELL, P .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1974, 77 (02) :C37-C39

[6] SYNTHESIS AND CHARACTERIZATION OF (PENTADIENYL)(TRICARBONYL)IRON(+1) CATIONS [J].

DONALDSON, WA ;

RAMASWAMY, M .

SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY, 1987, 17 (01) :49-56

[7]

DONALDSON WA, 1989, TETRAHEDRON LETT, P1343

[8]

DONALDSON WA, 1988, TETRAHEDRON LETT, P1343

[9] SUBSTITUENT EFFECTS IN C-13 NMR-SPECTRA OF IRON CARBONYL-COMPLEXES WITH ORGANIC PI-DONORS [J].

GIBSON, DH ;

ONG, TS .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1978, 155 (02) :221-228

[10] PROTOTROPIC REARRANGEMENTS OF UNSATURATED-HYDROCARBONS PROMOTED BY IRON CARBONYLS [J].

GIBSON, DH ;

ONG, TS ;

KHOURY, FG .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1978, 157 (01) :81-90

← 1 2 3 →