1ST CHARACTERIZATION OF A TETRATHIOMOLYBDATE(V) DERIVATIVE BY EPR, UV-VIS AND IR SPECTROELECTROCHEMISTRY

被引：13

作者：

SCHAFER, R

FIEDLER, J

MOSCHEROSCH, M

KAIM, W

机构：

[1] UNIV STUTTGART, INST ANORGAN CHEM, PFAFFENWALDRING 55, W-7000 STUTTGART 80, GERMANY

[2] CZECHOSLOVAK ACAD SCI, J HEYROVSKY INST PHYS CHEM & ELECTROCHEM, CS-18223 PRAGUE, CZECHOSLOVAKIA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 11期

关键词：

D O I：

10.1039/c39930000896

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The trinuclear complex ion [(NC)(OC)3Re(MoS4)Re(CO)3(CN)]2- 1(2-) is reversibly reduced to a Mo(V) containing trianion 1(3-), which exhibits hypsochromically shifted charge-transfer bands, bathochromically shifted CN, CO and MoS stretching frequencies and an axial EPR signal with g(parallel-to) > g(perpendicular-to).

引用

页码：896 / 897

页数：2

共 16 条

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