SOME COMPLEXES OF NEOPENTYLCADMIUM SPECIES WITH DITHIO-AND DI-SELENOCARBAMATES - THE SYNTHESIS, CHARACTERIZATION AND SINGLE-CRYSTAL X-RAY STRUCTURE OF A MIXED NEOPENTYL/DIETHYLDISELENOCARBAMATE OF CADMIUM - [(CH3)(3)CCH(2)CDSE(2)CNET(2)](2)

被引：19

作者：

ABRAHAMS, I

MALIK, A

MOTEVALLI, M

OBRIEN, P

机构：

[1] Department of Chemistry, Queen Mary and Westfield College, University of London, London, E1 4NS, Mile End Rd

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1994年 / 465卷 / 1-2期

关键词：

CADMIUM; NEOPENTYL; DITHIOCARBAMATE; DISELENOCARBAMATE; CRYSTAL STRUCTURE;

D O I：

10.1016/0022-328X(94)87038-1

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis and characterization of the neopentyl complexes of cadmium (CH3)(3)CH(2)CCdE(2)CNEt(2) (E = S or Se) and the related mixed metal species (CH3)(3)CH(2)CZn(0.5)Cd(0.5)Se(2)CNEt(2) are reported. A single crystal X-ray structure determination on for (CH3)(3)CH(2)CCdSe(2)CNEt(2); the compound is dimeric. All of the complexes decompose to give the corresponding binary or ternary metal chalcogenides.

引用

页码：73 / 77

页数：5

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