THE PREPARATION AND SOLID-STATE STRUCTURE OF RU5C(CO)(13)(ETA(4)-C(4)PH(4)) - THE FIRST CLUSTER TO CARRY A CYCLOBUTADIENE RING

被引：11

作者：

BAILEY, PJ ^{[1
]}

BLAKE, AJ ^{[1
]}

DYSON, PJ ^{[1
]}

INGHAM, SL ^{[1
]}

JOHNSON, BFG ^{[1
]}

机构：

[1] UNIV EDINBURGH,DEPT CHEM,EDINBURGH EH9 3JJ,MIDLOTHIAN,SCOTLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 19期

关键词：

D O I：

10.1039/c39940002233

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The new organometallic pentaruthenium cluster Ru5C(CO)(13)(eta(4)-C(4)Ph(4)) has been prepared from the redox mediated ligand transfer reaction between [Ru5C(CO)(14)](2-) and [Pd(eta(4)-C(4)Ph(4)) (acetone)(3)](2+) du ri ng wh ich the four-membered ri ng transfers from the palladium cation to a cluster ruthenium atom; the cluster has been characterised by single-crystal X-ray diffraction.

引用

页码：2233 / 2234

页数：2

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