AN ELECTRICALLY CONDUCTING POLYESTER THAT HAS ISOLATED QUATRATHIOPHENE UNITS IN THE MAIN-CHAIN

被引:57
作者
HONG, YL [1 ]
MILLER, LL [1 ]
机构
[1] UNIV MINNESOTA,DEPT CHEM,MINNEAPOLIS,MN 55455
关键词
D O I
10.1021/cm00059a003
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The polyester was oxidized in solution and in films to provide a rare example of an electrically conducting polymer that has alternating conjugated and nonconjugated main chain segments. This polymer cannot conduct via polarons/bipolarons but can conduct via pi-stacks formed by aggregation of the oxidized oligothiophene units. Thus it has structural features of both small molecule, 1-dimensional conductors, and conducting polymers.
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页码:1999 / &
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