STEREOSPECIFIC INTRAMOLECULAR FORMYL TRANSFER VIA RADICAL CYCLIZATION-FRAGMENTATION - PREPARATION OF ALKYL 2-DEOXY-2-ALPHA-FORMYLGLUCOPYRANOSIDES AND SIMILAR COMPOUNDS

被引：32

作者：

JUNG, ME

CHOE, SWT

机构：

[1] Department of Chemistry and Biochemistry, University of California, Los Angeles

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 39期

关键词：

D O I：

10.1016/S0040-4039(00)73722-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An efficient synthesis of alkyl 2-deoxy-2alpha-formylglucopyranosides is described. The key step involves a novel stereospecific intramolecular formyl transfer via a radical cyclization-fragmentation process in good yield.

引用

页码：6247 / 6250

页数：4

共 14 条

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