THE SYNTHESIS, MOLECULAR AND CRYSTAL-STRUCTURE OF THE BIS(ARENE) HEXARUTHENIUM CARBIDO-CARBONYL ISOMERS RU6C(CO)(11)(C(6)H(4)ME(2)-1,3)(C(6)H(5)ME)

被引：8

作者：

DYSON, PJ

JOHNSON, BFG

BRAGA, D

GREPIONI, F

MARTIN, CM

PARISINI, E

机构：

[1] UNIV EDINBURGH,DEPT CHEM,EDINBURGH EH9 3JJ,MIDLOTHIAN,SCOTLAND

[2] UNIV BOLOGNA,DIPARTIMENTO CHIM G CIAMICIAN,I-40126 BOLOGNA,ITALY

来源：

INORGANICA CHIMICA ACTA | 1995年 / 235卷 / 1-2期

关键词：

CRYSTAL STRUCTURES; RUTHENIUM COMPLEXES; ARENE COMPLEXES; CARBIDO COMPLEXES; CARBONYL COMPLEXES;

D O I：

10.1016/0020-1693(95)90084-J

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of Ru6C(CO)(14)(eta(6)-C(6)H(4)Me(2)-1,3) (1) with dihydrotoluene (C(6)H(7)Me) and Me(3)NO in dichloromethane yields Ru6C(CO)(12)(eta(6)-C(6)H(4)Me(2)-1,3)(mu(2)-C(6)H(7)Me) (2), Ru6C(Co)(11)(eta(6)-C(6)H(4)Me(2)-1,3)(mu(3)-C(6)H(5)Me (3) and cis-Ru6C(CO)(11)(eta(6)-C(6)H(4)Me(2)-1,3)(eta(6)-C(6)H(5)Me) (4). Reaction of 1 with toluene and Me(3)NO in dichloromethane-acetone affords trans-Ru6C(CO)(11)(eta(6)-C(6)H(4)Me(2)-1,3)(eta(6)-C(6)H(5)Me) (5). On standing at room temperature 3 isomerises spontaneously to 4. The molecular structures of 4 and 5 have been established by X-ray crystallography.

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页码：413 / 420

页数：8

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