SYNTHESIS AND STRUCTURE OF [ET2OZN(SC6H2TBU3)2], THE 1ST T-SHAPED ZINC COMPLEX

被引：36

作者：

POWER, PP

SHONER, SC

机构：

[1] Department of Chemistry, University of California, Davis, California

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1990年 / 29卷 / 12期

关键词：

D O I：

10.1002/anie.199014031

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The stacking of aryl groups once again appears to be structure-determining. The title complex, which is accessible by reaction of [Zn(CH2SiMe3)2] with two equivalents of 2,4,6-tBuC6H-2SH in the presence of Et2O, has an S-Zn-S angle of ca. 160-degrees and Zn-S distances of only 2.196 angstrom. In contrast, the Zn-O distance is relatively large and explains the ready cleavability of the ether ligands. Zinc thiolates are of interest as model complexes for zinc-containing proteins.

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页码：1403 / 1404

页数：2

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