IRIDIUM-CATALYZED REACTION OF ACETYLENE HYDRAZONES WITH A HYDROSILANE AND CARBON-MONOXIDE - SYNTHESIS OF NITROGEN-HETEROCYCLES

被引：21

作者：

CHATANI, N ^{[1
]}

YAMAGUCHI, S ^{[1
]}

FUKUMOTO, Y ^{[1
]}

MURAI, S ^{[1
]}

机构：

[1] OSAKA UNIV,FAC ENGN,DEPT APPL CHEM,SUITA,OSAKA 565,JAPAN

来源：

ORGANOMETALLICS | 1995年 / 14卷 / 09期

关键词：

D O I：

10.1021/om00009a053

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction. of acetylene hydrazones with a hydrosilane and carbon monoxide (CO) in the presence of Ir-4(CO)(12) as the catalyst gave six- or seven-membered nitrogen heterocycles having a (tert-butyldimethylsilyl)methylene group at the 3-position.

引用

页码：4418 / 4420

页数：3

共 25 条

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[7] HYDROSILYLATION OF PHENYLACETYLENE CATALYZED BY [IR(COD)(ETA(2)-(I)PR(2)PCH(2)CH(2)OME)][BF4]
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[8] SOLVENT-FREE CYCLIZATION OF LINEAR DIENES USING OLEFIN METATHESIS AND THE THORPE INGOLD EFFECT
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[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (27) : 10978 - 10980
[9] RING-OPENING SILYLFORMYLATION OF OXETANES CATALYZED BY [RHCL(CO)(2)](2)-AMINE
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[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1995, 489 (1-2) : 215 - 219
[10] RHODIUM-CATALYZED RING-OPENING SILYLFORMYLATION OF EPOXIDES LEADING TO BETA-SILOXY ALDEHYDES
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