RHODIUM-CATALYZED RING-OPENING SILYLFORMYLATION OF EPOXIDES LEADING TO BETA-SILOXY ALDEHYDES

被引：26

作者：

FUKUMOTO, Y ^{[1
]}

CHATANI, N ^{[1
]}

MURAI, S ^{[1
]}

机构：

[1] OSAKA UNIV,FAC ENGN,DEPT APPL CHEM,SUITA,OSAKA 565,JAPAN

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1993年 / 58卷 / 16期

关键词：

D O I：

10.1021/jo00068a004

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

In the presence of [RhCl(CO)2]2 and 1-methylpyrazole, the reaction of epoxides with a hydrosilane and carbon monoxide resulted in ring-opening silylformylation leading to beta-siloxy aldehydes.

引用

页码：4187 / 4188

页数：2

共 26 条

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