ALLYLATION OF IMIDAZOLES - THE BENEFICIAL EFFECT OF IMIDAZOLE LIGANDS ON (PI-ALLYL)NICKEL COUPLING

被引：26

作者：

KNAPP, S

ALBANEZE, J

SCHUGAR, HJ

机构：

[1] Department of Chemistry, Rutgers-The State University of New Jersey, New Brunswick

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1993年 / 58卷 / 05期

关键词：

D O I：

10.1021/jo00057a006

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The coupling of (pi-allyl)nickel halide complexes with iodoimidazoles proceeds efficiently in toluene solution without the use of coordinating solvent or added ligand. Nickel-promoted allylation, and symmetrical coupling, of non-imidazole aryl halides is enhanced by using N-methylimidazole as an additive.

引用

页码：997 / 998

页数：2