NEW PORPHYCENE LIGANDS - OCTAETHYLPORPHYCENE AND ETIOPORPHYCENE (OEPC AND ETIOPC) TETRACOORDINATED AND PENTACOORDINATED ZINC-COMPLEXES OF OEPC

被引：129

作者：

VOGEL, E ^{[1
]}

KOCH, P ^{[1
]}

HOU, XL ^{[1
]}

LEX, J ^{[1
]}

LAUSMANN, M ^{[1
]}

KISTERS, M ^{[1
]}

AUKAULOO, MA ^{[1
]}

RICHARD, P ^{[1
]}

GUILARD, R ^{[1
]}

机构：

[1] UNIV BOURGOGNE,FAC SCI GABRIEL,SYNTH & ELECTROSYNTH ORGANOMET LAB,CNRS,UA 33,F-21100 DIJON,FRANCE

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1993年 / 32卷 / 11期

关键词：

D O I：

10.1002/anie.199316001

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Steric interactions of the substituents weaken the strong NH … N hydrogen bonds (typical for porphycenes) in 1 (R = Me, Et) by increasing the N … N distance. As a consequence the coordination of metal ions, in particular of Zn2+ ions, is facilitated. These findings can be expected to give impetus to the research into metalloporphycenes. (Figure Presented.) Copyright © 1993 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：1600 / 1604

页数：5

共 37 条

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