DIASTEREOSELECTIVE PERFLUOROALKYLATION OF CHIRAL IMIDE ENOLATES WITH PERFLUOROALKYL IODIDES MEDIATED BY TRIETHYLBORANE

被引：14

作者：

ISEKI, K

TAKAHASHI, M

ASADA, D

NAGAI, T

KOBAYASHI, Y

机构：

[1] MEC Laboratory, Daikin Industries Ltd., Tsukuba, Ibaraki, 305, Miyukigaoka

来源：

JOURNAL OF FLUORINE CHEMISTRY | 1995年 / 74卷 / 02期

关键词：

DIASTEREOSELECTIVE PERFLUOROALKYLATION; CHIRAL IMIDE ENOLATES; PERFLUOROALKYL IODIDES; TRIETHYLBORANE;

D O I：

10.1016/0022-1139(95)03273-G

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The perfluoroalkylation of lithium enolates of chiral N-acyloxazolidinones with perfluoroalkyl iodides mediated by triethylborane proceeds with good diastereomeric excess (55%-93% de).

引用

页码：269 / 271

页数：3

共 8 条

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[4] DIASTEREOSELECTIVE TRIFLUOROMETHYLATION OF CHIRAL IMIDE ENOLATES WITH IODOTRIFLUOROMETHANE MEDIATED BY TRIETHYLBORANE
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[8] TRIETHYLBORANE-INDUCED STEREOSELECTIVE RADICAL-ADDITION OF PERFLUOROALKYL IODIDES TO ACETYLENES
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