THE SYNTHESIS OF FERROCENYL COMPOUNDS WITH 2ND-ORDER OPTICAL NONLINEARITIES

被引：61

作者：

BUNTING, HE

GREEN, MLH

MARDER, SR

THOMPSON, ME

BLOOR, D

KOLINSKY, PV

JONES, RJ

机构：

[1] QUEEN MARY COLL,DEPT PHYS,LONDON UE1 4NS,ENGLAND

[2] GEC RES LABS,HIRST RES CTR E LANE,WEMBLEY HA9 7PP,MIDDX,ENGLAND

来源：

POLYHEDRON | 1992年 / 11卷 / 12期

关键词：

D O I：

10.1016/S0277-5387(00)83142-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A series of new donor-acceptor compounds of the form (eta-C5H5)Fe(eta-C5H4) CH = CHR, where R is a pi-acceptor group and the ferrocenyl moiety is a donor has been synthesized. Reaction of the ylide (eta-C5H5)Fe(eta-C5H4)CH = P(C6H5)3 (3), generated in situ with various aldehydes, proceeds smoothly. The ferrocenyl compounds were screened for second harmonic generation efficiencies using 1.907-mu-m light generated by Raman shifting the 1.064-mu-m light from an Nd-YAG laser, using a high pressure hydrogen cell. Several of the compounds had efficiencies greater than the urea reference standard.

引用

页码：1489 / 1499

页数：11

共 39 条

[31] ASYMMETRIC CYCLOPALLADATION OF DIMETHYLAMINOMETHYLFERROCENE [J].

SOKOLOV, VI ;

TROITSKAYA, LL ;

REUTOV, OA .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1979, 182 (04) :537-546

[32]

Tam W., 1988, Proceedings of the SPIE - The International Society for Optical Engineering, V971, P107, DOI 10.1117/12.948221

[33] OXIDATIVE ADDITION OF PD(0) AND PT(0) WITH AROMATIC HALIDES - MATERIAL FOR 2ND-HARMONIC GENERATION [J].

TAM, W ;

CALABRESE, JC .

CHEMICAL PHYSICS LETTERS, 1988, 144 (01) :79-82

[34] DISPERSION OF THE NONLINEAR 2ND-ORDER OPTICAL SUSCEPTIBILITY OF ORGANIC-SYSTEMS [J].

TENG, CC ;

GARITO, AF .

PHYSICAL REVIEW B, 1983, 28 (12) :6766-6773

[35]

TOMA S, 1985, CHEM ZVESTI, V39, P115

[36] STABLE CARBONIUM-IONS .4. TORSIONAL BARRIERS IN SECONDARY AND TERTIARY FERROCENYLALKYLIUM LONS [J].

TURBITT, TD ;

WATTS, WE .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1974, (02) :177-184

[37] ORGANIC POLYMERIC AND NON-POLYMERIC MATERIALS WITH LARGE OPTICAL NONLINEARITIES [J].

WILLIAMS, DJ .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1984, 23 (09) :690-703

[38]

Williams VJ, 1993, NONLINEAR OPTICAL PR

[39]

WRIGHT ME, 1991, ACS SYM SER, V455, P602

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