CYCLOPENTADIENYL COMPOUNDS WITH NITROGEN DONORS IN THE SIDE-CHAIN

被引：168

作者：

JUTZI, P

SIEMELING, U

机构：

[1] Fakultät für Chemie der Universität Bielefeld, D-33615 Bielefeld

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1995年 / 500卷 / 1-2期

关键词：

N-FUNCTIONALIZED CYCLOPENTADIENYL; MAGNESIUM; GERMANIUM; TITANIUM; ZIRCONIUM; RHODIUM;

D O I：

10.1016/0022-328X(95)00514-Q

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The coordination chemistry of cyclopentadienyl ligands bearing either a dimethylaminoethyl side-chain or a pendant pyridyl group is described. The influence of these N donor functionalities on the structure and the physical as well. as chemical properties of relevant metal complexes is discussed. In several cases, a relatively weak intramolecular coordination of the pendant amine is found; the hemilabile coordination profile of the N functionalised cyclopentadienyl ligands towards d-block elements may prove useful for the development of single-component catalysts.

引用

页码：175 / 185

页数：11

共 121 条

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