ASYMMETRIC PALLADIUM-CATALYZED NUCLEOPHILIC-SUBSTITUTION OF RACEMIC 1-NAPHTHYLETHYL ESTERS

被引：42

作者：

LEGROS, JY

TOFFANO, M

FIAUD, JC

机构：

[1] Laboratoire de Synthèse Asymétrique Associé au C.N.R.S. (URA n 1497), Institut de Chimie Moléculaire d'Orsay, Université de Paris-Sud, 91405 Orsay

来源：

TETRAHEDRON-ASYMMETRY | 1995年 / 6卷 / 08期

关键词：

D O I：

10.1016/0957-4166(95)00247-M

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The asymmetric palladium-catalyzed reaction of racemic 1-naphthylethyl acetates by nucleophiles gave substitution products with up to 61.5% enantioselectivity. The influences of the chiral ligand, temperature, nature of the leaving group of the substrate and of the nucleophile were studied.

引用

页码：1899 / 1902

页数：4

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