POLYANILINE DISPERSIONS .4. POLYMERIZATION SEEDED BY POLYANILINE PARTICLES

被引：38

作者：

STEJSKAL, J

SPIRKOVA, M

KRATOCHVIL, P

机构：

[1] Institute of Macromolecular Chemistry, Academy of Sciences of the Czech Republic, Prague

来源：

ACTA POLYMERICA | 1994年 / 45卷 / 05期

关键词：

D O I：

10.1002/actp.1994.010450509

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Aniline hydrochloride was polymerized in water and in 1 M hydrochloric acid by oxidation with ammonium persulfate. The macroscopic precipitation of polyaniline was prevented by the presence of poly(vinyl alcohol). The changes of pH occurring during the reaction were recorded. Their relation to color transitions is discussed. The reaction was accelerated by introduction of seed polyaniline particles. The properties of resulting dispersions were not affected by seeding. The particle diameter was about 310 nm for polymerization in water and about 420 nm in 1 M hydrochloric acid.

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页码：385 / 388

页数：4

相关论文

共 34 条

[1] IS THERE A COLLOID IN EVERY SOLUTION-PROCESSABLE CONDUCTING POLYMER [J].

ALDISSI, M .

ADVANCED MATERIALS, 1993, 5 (01) :60-62

[2] OPTIMUM REACTION CONDITIONS FOR THE POLYMERIZATION OF ANILINE IN AQUEOUS-SOLUTION BY AMMONIUM PERSULFATE [J].

ARMES, SP ;

MILLER, JF .

SYNTHETIC METALS, 1988, 22 (04) :385-393

[3]

Barrett K. E. J., 1975, DISPERSION POLYM ORG

[4] KINETICS OF DISPERSION POLYMERIZATION OF SOLUBLE MONOMERS .I. METHYL METHACRYLATE [J].

BARRETT, KEJ ;

THOMAS, HR .

JOURNAL OF POLYMER SCIENCE PART A-1-POLYMER CHEMISTRY, 1969, 7 (9PA1) :2621-&

[5]

BATES RG, 1961, REFERENCE ELECTRODES, P239

[6] SYNTHESIS OF NOVEL POLYANILINE COLLOIDS USING CHEMICALLY GRAFTED POLY(N-VINYLPYRROLIDONE)-BASED STABILIZERS [J].

DEARMITT, C ;

ARMES, SP .

JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1992, 150 (01) :134-142

[7] POLYANILINE - A HISTORICAL SURVEY [J].

GENIES, EM ;

BOYLE, A ;

LAPKOWSKI, M ;

TSINTAVIS, C .

SYNTHETIC METALS, 1990, 36 (02) :139-182

[8] PREPARATION AND CHARACTERIZATION OF AQUEOUS POLYANILINE DISPERSIONS [J].

GOSPODINOVA, N ;

TERLEMEZYAN, L ;

MOKREVA, P ;

STEJSKAL, J ;

KRATOCHVIL, P .

EUROPEAN POLYMER JOURNAL, 1993, 29 (10) :1305-1309

[9] ON THE MECHANISM OF OXIDATIVE POLYMERIZATION OF ANILINE [J].

GOSPODINOVA, N ;

TERLEMEZYAN, L ;

MOKREVA, P ;

KOSSEV, K .

POLYMER, 1993, 34 (11) :2434-2437

[10] CHEMICAL OXIDATIVE POLYMERIZATION OF ANILINE IN AQUEOUS-MEDIUM WITHOUT ADDED ACIDS [J].

GOSPODINOVA, N ;

MOKREVA, P ;

TERLEMEZYAN, L .

POLYMER, 1993, 34 (11) :2438-2439

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