THE SYNTHESIS OF OPTICALLY-ACTIVE 2-PHENYLTHIO ALDEHYDES

被引:32
作者
CHIBALE, K [1 ]
WARREN, S [1 ]
机构
[1] UNIV CAMBRIDGE,CHEM LABS,CAMBRIDGE CB2 1EW,ENGLAND
关键词
D O I
10.1016/S0040-4039(00)76722-0
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Optically active linear and branched chain 2-phenylthio aldehydes can be made in high optical purity (up to >98% e.e.) by sulfenylation of a phenylalanine-derived oxazolidinone imide, reduction and re-oxidation with the Dess-Martin reagent even though the products enolise easily.
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页码:3991 / 3994
页数:4
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