SELECTIVE FORMATION OF CIS-PHCH=CH(SIET(3)) BY REACTION OF PHC-CH WITH THE STOICHIOMETRIC AMOUNT OF HSIET(3), IN THE PRESENCE OF RUTHENIUM CATALYSTS

被引：19

作者：

ESTERUELAS, MA

LOPEZ, AM

ORO, LA

TOLOSA, JI

机构：

[1] Departamento de Química Inorgánica, Instituto de Ciencia de Materiales de Aragón, Universidad de Zaragoza

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 1995年 / 96卷 / 01期

关键词：

HYDROSILYLATION; RUTHENIUM;

D O I：

10.1016/1381-1169(94)00046-8

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The complexes MH(eta(2)-H2BH2)(CO)(PPr3i)(2), M(C(2)Ph)(2)(CO)(PPr3i)(2) and M(eta(2)-C(2)Ph(2))(CO)(PPr3i)(2)(M=Ru, Os) are found to be very active and highly selective catalysts for the reaction of PhC=CH with the stoichiometric amount of HSiEt(3); in the presence of the ruthenium catalysts, the reactions lead to cis-PhCH=CH(SiEt(3)) with selectivities of about 95%.

引用

页码：21 / 23

页数：3

共 26 条

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