A REAGENT FOR DETERMINING OPTICAL PURITIES OF DIOLS BY FORMATION OF DIASTEREOMERIC ARYLBORONATE ESTERS

被引：28

作者：

BURGESS, K

PORTE, AM

机构：

[1] Department of Chemistry, Texas A & M University, College Station, Texas

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1994年 / 33卷 / 11期

关键词：

D O I：

10.1002/anie.199411821

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A remarkably simple arylboronic acid reagent for derivatization of diols enables the determination of the optical purity of diols by 1H NMR spectroscopy by the formation of the corresponding esters 1. This procedure could be particularly valuable as enantioselective bishydroxylations become more widely used for asymmetric syntheses. (Figure Presented.) Copyright © 1994 by VCH Verlagsgesellschaft mbH, Germany

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页码：1182 / 1184

页数：3

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