HETEROLYTIC C,O-BOND CLEAVAGE OF 4'-NUCLEOTIDE RADICALS

被引：33

作者：

GIESE, B ^{[1
]}

ERDMANN, P ^{[1
]}

GIRAUD, L ^{[1
]}

GOBEL, T ^{[1
]}

PETRETTA, M ^{[1
]}

SCHAFER, T ^{[1
]}

VONRAUMER, M ^{[1
]}

机构：

[1] UNIV FRIBOURG, INST PHYS CHEM, CH-1700 FRIBOURG, SWITZERLAND

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 17期

关键词：

D O I：

10.1016/S0040-4039(00)77005-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Photolysis of selenoacetals 7-10 and acylselenides 13 and 14 generates 4'-deoxyribonucleotide radicals. Photocurrent experiments show that radicals with a phosphate group in beta-position give rise to a heterolytical bond cleavage.

引用

页码：2683 / 2686

页数：4

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