SYNTHESIS OF METHACRYLATE MONOMERS FROM ALKYNES AND ARENEALKENYLRUTHENIUM(II) CATALYST

被引：12

作者：

LAVASTRE, O ^{[1
]}

DIXNEUF, PH ^{[1
]}

机构：

[1] UNIV RENNES 1,CHIM COORDINAT ORGAN LAB,CNRS,URA 415,F-35042 RENNES,FRANCE

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1995年 / 488卷 / 1-2期

关键词：

ARENE COMPLEXES; ALKENYL COMPLEXES; RUTHENIUM; METHACRYLATE MONOMERS; SYNTHESIS;

D O I：

10.1016/0022-328X(94)00030-G

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The alkenyl derivatives [(C(6)Me(6))(PMe(3))ClRu-C(OMe)=CHR] IIIa (R = Me) and IIIb (R = Ph) have been prepared by deprotonation of the corresponding carbene complexes [(C(6)Me(6))(PMe(3))ClRu=C(OMe)CH(2)R][PF6-] II with Me(3)COK. Complexes III can be used as efficient catalysts for the addition of functional carboxylic acids to terminal alkynes to give dioxolanone 4, from R(-)mandelic acid, or methacrylates of the type CH2=C(Me)CO-OY: Y = C(=CH2)(n)Bu, 6, CH2CH2C=CH, 8, or C(=CH2)CH2CH2CH2CH2C(=CH2)OCOC(Me)=CH2, 10.

引用

页码：C9 / C10

页数：2

共 10 条

[1] RUTHENIUM-CATALYZED ADDITIONS TO ALKYNES - SYNTHESIS OF ACTIVATED ESTERS AND THEIR USE IN ACYLATION REACTIONS
BRUNEAU, C
NEVEUX, M
KABOUCHE, Z
RUPPIN, C
DIXNEUF, PH
[J]. SYNLETT, 1991, (11) : 755 - 763
[2] NOVEL EFFICIENT SYNTHESIS OF 1-ETHOXYVINYL ESTERS USING RUTHENIUM CATALYSTS AND THEIR USE IN ACYLATION OF AMINES AND ALCOHOLS - SYNTHESIS OF HYDROPHILIC 3'-N-ACYLATED OXAUNOMYCIN DERIVATIVES
KITA, Y
MAEDA, H
OMORI, K
OKUNO, T
TAMURA, Y
[J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1993, (23): : 2999 - 3005
[3] LAVASTRE O, 1994, ORGANOMETALLICS, P2500
[4] LAVASTRE O, UNPUB
[5] ACTIVATION OF 1-ALKYNES BY HEXAMETHYLBENZENE RUTHENIUM(II) DERIVATIVES - SYNTHESIS AND CHARACTERIZATION OF ALKOXYALKYLCARBENE RUTHENIUM(II) COMPLEXES VIA HIGHLY REACTIVE VINYLIDENE INTERMEDIATES
LEBOZEC, H
OUZZINE, K
DIXNEUF, PH
[J]. ORGANOMETALLICS, 1991, 10 (08) : 2768 - 2772
[6] SELECTIVE ADDITION OF UNSATURATED CARBOXYLIC-ACIDS TO TERMINAL ACETYLENES CATALYZED BY BIS(ETA-5-CYCLOOCTADIENYL)RUTHENIUM(II)-TRI-NORMAL-BUTYL-PHOSPHINE - A NOVEL SYNTHESIS OF ENOL ESTERS
MITSUDO, T
HORI, Y
WATANABE, Y
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1985, 50 (09) : 1566 - 1568
[7] ENOL FORMATES - RUTHENIUM CATALYZED FORMATION AND FORMYLATING REAGENTS
NEVEUX, M
BRUNEAU, C
DIXNEUF, PH
[J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1991, (05): : 1197 - 1199
[8] NOVEL RUTHENIUM-CATALYZED SYNTHESIS OF 1,3-DIOXOLAN-4-ONES FROM ALPHA-HYDROXY ACIDS AND TERMINAL ALKYNES VIA ENOL ESTERS
NEVEUX, M
SEILLER, B
HAGEDORN, F
BRUNEAU, C
DIXNEUF, PH
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1993, 451 (1-2) : 133 - 138
[9] OUZZINE K, 1988, THESIS U RENNES
[10] RUPPIN C, 1986, TETRAHEDRON LETT, V52, P6323

← 1 →