NOVEL RUTHENIUM-CATALYZED SYNTHESIS OF 1,3-DIOXOLAN-4-ONES FROM ALPHA-HYDROXY ACIDS AND TERMINAL ALKYNES VIA ENOL ESTERS

被引：51

作者：

NEVEUX, M ^{[1
]}

SEILLER, B ^{[1
]}

HAGEDORN, F ^{[1
]}

BRUNEAU, C ^{[1
]}

DIXNEUF, PH ^{[1
]}

机构：

[1] UNIV RENNES 1,CNRS,CHIM COORDINAT ORGAN LAB,CAMPUS BEAULIEU,F-35042 RENNES,FRANCE

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1993年 / 451卷 / 1-2期

关键词：

D O I：

10.1016/0022-328X(93)83017-P

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Alpha-Hydroxy acids react with terminal alkynes, in the presence of binuclear ruthenium complexes [Ru(mu-O2CR)(CO)2(PPh3)]2 as catalyst precursors, to selectively afford either alpha-hydroxy enol esters or their cyclization products 1,3-dioxolan-4-ones.

引用

页码：133 / 138

页数：6

共 21 条

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