SYNTHESIS OF TRIS(TETRAMETHYLCYCLOPENTADIENYL) DERIVATIVES OF THE ACTINIDE METALS - MOLECULAR-STRUCTURE OF [UCL(ETA-C5ME4H)3]

被引：30

作者：

CLOKE, FGN ^{[1
]}

HAWKES, SA ^{[1
]}

HITCHCOCK, PB ^{[1
]}

SCOTT, P ^{[1
]}

机构：

[1] UNIV SUSSEX,SCH CHEM & MOLEC SCI,BRIGHTON BN1 9QJ,E SUSSEX,ENGLAND

来源：

ORGANOMETALLICS | 1994年 / 13卷 / 07期

关键词：

D O I：

10.1021/om00019a053

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of [Li(C5Me4H)] with MCl4 (M = U, Th) in tetrahydrofuran gives highly sterically congested tris(tetramethylcyclopentadienyl)actinide(IV) derivatives which have been characterized by variable-temperature NMR studies and, in the case of the uranium compound, by X-ray crystallography.

引用

页码：2895 / 2897

页数：3

共 10 条

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