FREE RADICAL-INDUCED C-ALLYLATION OF ALPHA-BROMOLACTONES - SYNTHESIS OF 2-C-ALLYL-2-DEOXY-D-ARABINONO-1,4-LACTONE AND 2-C-ALLYL-2-DEOXY-D-RIBONO-1,4-LACTONE

被引：7

作者：

HANESSIAN, S

LEGER, R

ALPEGIANI, M

机构：

[1] Department of Chemistry, Université de Montréal, Succ. A. Montrel, Que. H3C 3J7

来源：

CARBOHYDRATE RESEARCH | 1992年 / 228卷 / 01期

关键词：

D O I：

10.1016/S0008-6215(00)90556-1

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

Application of the Keck C-allylation of organic halides to 2-bromo-2-deoxy-D-arabinonolactone resulted in the formation of mixtures of 2-C-allyl lactones. The stereochemical preferences observed were dictated by the nature of vicinal and remotely placed substituents in the lactone.

引用

页码：145 / 155

页数：11

共 73 条

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