THE KINETIC RANGE OF CARBENE-PYRIDINE YLIDE FORMING REACTIONS

被引：31

作者：

GE, CS ^{[1
]}

JANG, EG ^{[1
]}

JEFFERSON, EA ^{[1
]}

LIU, WG ^{[1
]}

MOSS, RA ^{[1
]}

WLOSTOWSKA, J ^{[1
]}

XUE, S ^{[1
]}

机构：

[1] RUTGERS STATE UNIV,DEPT CHEM,NEW BRUNSWICK,NJ 08903

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 12期

关键词：

D O I：

10.1039/c39940001479

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Absolute rate constants for the ylide-forming reactions of 16 carbenes with pyridine range from 1.4 x 10(10) to 1.2 x 10(5) dm(3) mol(-1) s(-1), and can be rationalized by frontier molecular orbital theory.

引用

页码：1479 / 1480

页数：2

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