HETEROBIMETALLIC AGGREGATES OF COPPER(I) WITH THIOVANADATE - SYNTHESES AND CHARACTERIZATIONS OF (ET4N)3[VS4CU4(OC4H8DTC)N(PHS)4-N] (N = 0, 1, 2)

被引：21

作者：

YANG, Y

LIU, QT

HUANG, LG

WU, DX

KANG, BS

LU, JX

机构：

[1] CHINESE ACAD SCI,STATE KEY LAB STRUCT CHEM,FUZHOU 350002,PEOPLES R CHINA

[2] CHINESE ACAD SCI,FUJIAN INST RES STRUCT MATTER,FUZHOU 350002,PEOPLES R CHINA

来源：

INORGANIC CHEMISTRY | 1993年 / 32卷 / 24期

关键词：

D O I：

10.1021/ic00076a004

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Complexes containing the VS4Cu4 core and mixed ligands, R2dtc- and PhS-, were synthesized. The VS4Cu4 core has approximate D2d symmetry. The V-51 NMR spectra indicate that several disproportion reactions caused by ligand exchange are present in solution. 2[VS4CU4(R2dtc)n(PhS)4-n]3- half arrow right over half arrow left [VS4Cu4(R2dtc)n+1(PhS)3-n]3- + [VS4CU4(R2dtc)n-1(PhS)5-n]3- (n = 1.2)

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页码：5431 / 5432

页数：2

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