DIPOLE BINDING TO A STRONGLY POLAR MOLECULE AND ITS HOMOGENEOUS CLUSTERS - MAGIC DISTRIBUTION OF ACETONITRILE CLUSTER ANIONS

被引：71

作者：

DESFRANCOIS, C

ABDOULCARIME, H

ADJOURI, C

KHELIFA, N

SCHERMANN, JP

机构：

[1] Laboratoire de Physique des Lasers, Institut Galilée, Université Paris-Nord, Villetaneuse

来源：

EUROPHYSICS LETTERS | 1994年 / 26卷 / 01期

关键词：

D O I：

10.1209/0295-5075/26/1/005

中图分类号：

O4 [物理学];

学科分类号：

0702 ;

摘要：

We study charge transfer collisions between laser-excited xenon (nf, np) Rydberg atoms and acetonitrile molecules and clusters. CH3CN- and (CH3CN)3- anions are observed only in extremely narrow ranges of Rydberg n-values. The measurement of the electron binding energies of these anions shows that they are in dipole-bound states. The transition to solvated electron behaviour corresponds to the appearance of more strongly bound large anions (N > 10) which are created for a wide range of Rydberg-electron energies.

引用

页码：25 / 30

页数：6

共 30 条

[11] EXCITED-STATES OF POLAR NEGATIVE-IONS
GARRETT, WR
[J]. JOURNAL OF CHEMICAL PHYSICS, 1982, 77 (07) : 3666 - 3673
[12] THERMALLY STABLE NEGATIVE-IONS OF POLAR-MOLECULES
GARRETT, WR
[J]. JOURNAL OF CHEMICAL PHYSICS, 1978, 69 (06) : 2621 - 2626
[13] CRITICAL BINDING OF ELECTRON-DIPOLE ROTOR SYSTEMS - ELECTRONICALLY EXCITED-STATES
GARRETT, WR
[J]. JOURNAL OF CHEMICAL PHYSICS, 1980, 73 (11) : 5721 - 5725
[14] MULTIPLE-CROSSING ELECTRON-JUMP MODEL FOR REACTIONS OF METAL ATOMS WITH DIATOMIC HALOGEN MOLECULES
GISLASON, EA
SACHS, JG
[J]. JOURNAL OF CHEMICAL PHYSICS, 1975, 62 (07) : 2678 - 2684
[15] EXPERIMENTAL-OBSERVATION OF THE NEGATIVELY CHARGED WATER DIMER AND OTHER SMALL (H2O)N-CLUSTERS
HABERLAND, H
LUDEWIGT, C
SCHINDLER, HG
WORSNOP, DR
[J]. JOURNAL OF CHEMICAL PHYSICS, 1984, 81 (08) : 3742 - 3744
[16] FIELD DETACHMENT OF (H2O)2- CLUSTERED WITH RARE-GASES
HABERLAND, H
LUDEWIGT, C
SCHINDLER, HG
WORSNOP, DR
[J]. PHYSICAL REVIEW A, 1987, 36 (02): : 967 - 970
[17] ELECTRON-TRANSFER FROM LASER-EXCITED RYDBERG ATOMS TO MOLECULES - ABSOLUTE RATE CONSTANTS AT LOW AND INTERMEDIATE PRINCIPAL QUANTUM NUMBERS
HARTH, K
RUF, MW
HOTOP, H
[J]. ZEITSCHRIFT FUR PHYSIK D-ATOMS MOLECULES AND CLUSTERS, 1989, 14 (02): : 149 - 165
[18] OBSERVATION OF DIPOLE-BOUND CH3CN- FOLLOWING ELECTRON-ATTACHMENT TO CH3CN CLUSTERS
HASHEMI, R
ILLENBERGER, E
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1991, 95 (17) : 6402 - 6403
[19] ION-PAIR FORMATION IN ALKALI-HALOGEN COLLISIONS AT HIGH VELOCITIES
HUBERS, MM
KLEYN, AW
LOS, J
[J]. CHEMICAL PHYSICS, 1976, 17 (03) : 303 - 325
[20] EXCHANGE INTERACTION BETWEEN IONIC AND COVALENT STATES OF 2 ATOMS AT LARGE DISTANCES
JANEV, RK
SALIN, A
[J]. JOURNAL OF PHYSICS PART B ATOMIC AND MOLECULAR PHYSICS, 1972, 5 (02): : 177 - &

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