ELECTROCHEMICAL REGENERATION OF NICOTINAMIDE COFACTOR USING A POLYPYRROLE RHODIUM BIS-TERPYRIDINE MODIFIED ELECTRODE

被引：59

作者：

BELEY, M

COLLIN, JP

机构：

[1] Laboratoire de Chimie Organo-Minérale, URA 422 au CNRS, Faculté de Chimie, 67000 Strasbourg, 1, rue Blaise Pascal

来源：

JOURNAL OF MOLECULAR CATALYSIS | 1993年 / 79卷 / 1-3期

关键词：

ELECTROCATALYSIS; MODIFIED ELECTRODES; NICOTINAMIDE ADENINE DINUCLEOTIDE; POLYPYRROLE; RHODIUM; TERPYRIDINE DERIVATIVES;

D O I：

10.1016/0304-5102(93)85096-C

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A rhodium(III) bis-terpyridine complex covalently linked to two pyrrole groups has been electropolymerized on a reticulated vitreous carbon electrode. The resulting modified electrode has been used in the electrocatalytic reduction of nicotinamide adenine dinucleotide into 1,4-NADH. The efficiency of a system incorporating cyclohexanone as substrate and liver alcohol dehydrogenase as enzyme has demonstrated the feasibility of bioreactors with electrochemical regeneration of NADH cofactor.

引用

页码：133 / 140

页数：8

共 24 条

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