DETERMINATION OF TRACE LEVELS OF METAL-IONS IN WATER SAMPLES BY INDUCTIVELY-COUPLED PLASMA-MASS SPECTROMETRY AFTER ONLINE PRECONCENTRATION ON SO3-OXINE CM-CELLULOSE

被引:30
作者
HUANG, KS [1 ]
JIANG, SJ [1 ]
机构
[1] NATL SUN YAT SEN UNIV,DEPT CHEM,KAOHSIUNG 804,TAIWAN
来源
FRESENIUS JOURNAL OF ANALYTICAL CHEMISTRY | 1993年 / 347卷 / 6-7期
关键词
D O I
10.1007/BF00323965
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
A method utilizing a miniature chelated ion-exchanger column of SO3-oxine CM-cellulose has been developed to increase the sensitivity for multielement measurements by inductively coupled plasma mass spectrometry (ICP-MS). This matrix/analyte separation and preconcentration technique has been used to preconcentrate Mn, Co, Ni, Cu, Cd, and Pb from natural water samples. The multielement detection limits are in the low ppt (pg/mL) range. This FIA-ICP-MS method has been applied to the determination of various trace levels of metal ions in riverine reference material SLRS-2 and open ocean seawater reference material NASS-3.
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页码:238 / 242
页数:5
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