STRUCTURE OF A CONFINED FLUID OF HARD ELLIPSOIDS

被引：22

作者：

KALPAXIS, P

RICKAYZEN, G

机构：

[1] The Physics Laboratory, The University, Canterbury, Kent

来源：

MOLECULAR PHYSICS | 1993年 / 80卷 / 02期

关键词：

D O I：

10.1080/00268979300102331

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The density profiles of a fluid of hard ellipsoids confined to a slit are studied by means of a theoretical approach proposed by one of the authors [1]. A density functional is used in which the possible orientations of the molecules are restricted and in which a geometric approximation is made for the direct correlation function of the homogeneous fluid. Results are obtained for a range of densities and for both oblate and prolate ellipsoids of revolution. Monte Carlo simulations of the same system have also been performed and are found to agree well with the theory within the range of parameters studied.

引用

页码：391 / 406

页数：16

共 30 条

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