SYNTHESIS, MULTINUCLEAR NMR, AND SOLUTION CONFORMATION OF (ETA-5-INDENYL)COIRFL COMPLEXES (L = CO, P-DONOR)

被引：15

作者：

JABLONSKI, CR

ZHOU, ZX

机构：

来源：

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE | 1992年 / 70卷 / 10期

关键词：

D O I：

10.1139/v92-322

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The preparation, spectroscopic characterization, and conformational analysis of a series of Co(III) indenyl complexes, (C9H7)CoIRfL (R(f) = C3F7, C6F13, L = CO, P-donor), 2-8, are described. C-13 and H-1 NMR parameters are consistent with a slightly distorted eta5-C9H7 coordination. H-1 nuclear Overhauser effect difference (nOed) spectra indicate a preferred solution conformation in which the perfluoroalkyl group is trans to the C3a-C-7a ring junction.

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页码：2544 / 2551

页数：8

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