REACTIONS OF ACRYLIC-ACID WITH FLUOROALKANOYL PEROXIDES - THE FORMATION OF ACRYLIC-ACID OLIGOMERS CONTAINING 2 FLUOROALKYLATED END-GROUPS

被引：25

作者：

SAWADA, H ^{[1
]}

MINOSHIMA, Y ^{[1
]}

NAKAJIMA, H ^{[1
]}

机构：

[1] NIPPON OIL & FATS CORP,TSUKUBA RES LAB,TSUKUBA,IBARAKI 30026,JAPAN

来源：

JOURNAL OF FLUORINE CHEMISTRY | 1993年 / 65卷 / 1-2期

关键词：

D O I：

10.1016/S0022-1139(00)80491-1

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Fluoroalkylated acrylic acid oligomers were obtained by oligomerizations of acrylic acid with fluoroalkanoyl peroxides. Elemental analyses for fluorine showed that these oligomers contain two fluoroalkylated end-groups in one oligomeric molecule. Perfluoro-oxa-alkyl radicals produced by the decomposition of the corresponding peroxides have been demonstrated as being more stable than perfluoroalkyl radicals, and their higher stabilities explain the formation of higher molecular weight in the perfluoro-oxa-alkylated acrylic acid oligomers.

引用

页码：169 / 173

页数：5

共 13 条

[1]

HIGASHIMURA T, 1984, YUKI GOSEI KAGAKU KY, V42, P330

[2] STABILIZATION ENERGIES AND STRUCTURES OF SUBSTITUTED METHYL RADICALS [J].

PASTO, DJ ;

KRASNANSKY, R ;

ZERCHER, C .

JOURNAL OF ORGANIC CHEMISTRY, 1987, 52 (14) :3062-3072

[3] PERFLUOROPROPYLATION OF FURANS, THIOPHENES, AND PYRIDINES WITH BIS(HEPTAFLUOROBUTYRYL) PEROXIDE [J].

SAWADA, H ;

YOSHIDA, M ;

HAGII, H ;

AOSHIMA, K ;

KOBAYASHI, M .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1986, 59 (01) :215-219

[4] SYNTHESIS AND SURFACTANT PROPERTIES OF FLUOROALKYLATED OLIGOMERS CONTAINING CARBOXY GROUPS [J].

SAWADA, H ;

GONG, YF ;

MINOSHIMA, Y ;

MATSUMOTO, T ;

NAKAYAMA, M ;

KOSUGI, M ;

MIGITA, T .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1992, (07) :537-538

[5] TRIFLUOROMETHYLATION OF AROMATIC-COMPOUNDS WITH BIS(TRIFLUOROACETYL) PEROXIDE [J].

SAWADA, H ;

NAKAYAMA, M ;

YOSHIDA, M ;

YOSHIDA, T ;

KAMIGATA, N .

JOURNAL OF FLUORINE CHEMISTRY, 1990, 46 (03) :423-431

[6] SYNTHESIS OF AROMATIC-COMPOUNDS CONTAINING PERFLUORO-OXA-ALKYL GROUPS [J].

SAWADA, H ;

NAKAYAMA, M .

JOURNAL OF FLUORINE CHEMISTRY, 1991, 51 (01) :117-129

[7] SYNTHESIS OF PERFLUORO-OXA-ALKYLATED COMPOUNDS BY THE USE OF PERFLUORO-OXA-ALKANOYL PEROXIDES AND THEIR APPLICATIONS [J].

SAWADA, H .

JOURNAL OF FLUORINE CHEMISTRY, 1993, 61 (03) :253-272

[8]

SAWADA H, 1992, J JPN OIL CHEM SOC, V41, P537

[9]

Scherer Jr K.V., 1986, J FLUORINE CHEM, V33, P298

[10] F-2,4-DIMETHYL-3-ETHYL-3-PENTYL AND "F-2,4-DIMETHYL-3-ISOPROPYL-3-PENTYL - STABLE TERT-PERFLUOROALKYL RADICALS PREPARED BY ADDITION OF FLUORINE OR TRIFLUOROMETHYL TO A PERFLUOROALKENE [J].

SCHERER, KV ;

ONO, T ;

YAMANOUCHI, K ;

FERNANDEZ, R ;

HENDERSON, P ;

GOLDWHITE, H .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (03) :718-719

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