HETEROMETAL CUBOIDAL CLUSTERS MFE4S6(PET3)4CL (M = V, MO) - SYNTHESIS, STRUCTURAL-ANALYSIS BY CRYSTALLOGRAPHY AND EXAFS, AND RELEVANCE TO THE CORE STRUCTURE OF THE IRON MOLYBDENUM COFACTOR OF NITROGENASE

被引:66
作者
NORDLANDER, E
LEE, SC
CEN, W
WU, ZY
NATOLI, CR
DICICCO, A
FILIPPONI, A
HEDMAN, B
HODGSON, KO
HOLM, RH
机构
[1] HARVARD UNIV, DEPT CHEM, CAMBRIDGE, MA 02138 USA
[2] LAB NAZL FRASCATI, INFN, I-00044 FRASCATI, ITALY
[3] UNIV CAMERINO, DIPARTIMENTO MATEMAT & FIS, I-62032 CAMERINO, ITALY
[4] UNIV AQUILA, DIPARTIMENTO FIS, I-67010 Coppito, ITALY
[5] STANFORD UNIV, STANFORD SYNCHROTRON RADIAT LAB, STANFORD, CA 94305 USA
[6] STANFORD UNIV, DEPT CHEM, STANFORD, CA 94305 USA
关键词
D O I
10.1021/ja00066a024
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The cluster self-assembly system MCl3(THF)3/2FeCl2(PEt3)2/4-7(Me3Si)2S affords, after separation of cluster coproducts, the isomorphous compounds MFe4S6(PEt3)4Cl (M = V, Mo) in modest yields. These species were identified by spectroscopic methods and X-ray diffraction. The compounds crystallize in trigonal space group R3cBAR; the cluster molecules are isostructural and essentially isometric. They consist of a cuboidal Fe4S3 fragment that is bridged by three mu2-S atoms to a M-PEt3 unit whose M-P bond is coincident with an imposed C3 axis. Coordination is completed at the three symmetry-related Fe sites by PEt3 ligands and at the Fe site on the C3 axis by chloride. The trigonal pyramidal coordination units FeS3P and MoS3P are infrequently observed and unprecedented, respectively, and the cuboidal fragment has been observed previously only in several Fe-S-nitrosyl clusters. The cluster structure presents atoms at a series of distances from the M or Fe atoms and has been utilized in a detailed test of distance determinations in a new approach to the analysis of EXAFS data using theoretical phases and amplitudes (the GNXAS approach). The Mo and Fe EXAFS of the cluster MoFe4S6(PEt3)4Cl have been analyzed in detail and first coordination shell distances determined with high accuracy. The contribution of multiple scattering pathways in the EXAFS of the cluster has been evaluated. The relevance of the results to the FeMo-cofactor structure as recently deduced from protein crystallography is considered.
引用
收藏
页码:5549 / 5558
页数:10
相关论文
共 86 条
[51]   STRUCTURE OF THE 3FE-4S CLUSTER IN DESULFOVIBRIO-GIGAS FERREDOXIN-II [J].
KISSINGER, CR ;
ADMAN, ET ;
SIEKER, LC ;
JENSEN, LH .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (26) :8721-8723
[52]   HETEROMETALLIC CLUSTERS - SYNTHESIS AND REACTIONS OF VANADIUM-IRON-SULFUR SINGLES-CUBANE AND DOUBLE-CUBANE CLUSTERS AND THE STRUCTURE OF [V2FE6S8CL4(C2H4S2)2]4- [J].
KOVACS, JA ;
HOLM, RH .
INORGANIC CHEMISTRY, 1987, 26 (05) :702-711
[53]   STRUCTURAL CHEMISTRY OF VANADIUM-IRON-SULFUR CLUSTERS CONTAINING THE CUBANE-TYPE [VFE3S4]2+ CORE [J].
KOVACS, JA ;
HOLM, RH .
INORGANIC CHEMISTRY, 1987, 26 (05) :711-718
[54]   NATURAL WIDTHS OF ATOMIC K-LEVELS AND L-LEVELS,K-ALPHA X-RAY-LINES AND SEVERAL KLL AUGER LINES [J].
KRAUSE, MO ;
OLIVER, JH .
JOURNAL OF PHYSICAL AND CHEMICAL REFERENCE DATA, 1979, 8 (02) :329-338
[55]   GROUP-5 TETRATHIOMETALATES - SIMPLIFIED SYNTHESES AND STRUCTURES [J].
LEE, SC ;
LI, JG ;
MITCHELL, JC ;
HOLM, RH .
INORGANIC CHEMISTRY, 1992, 31 (21) :4333-4338
[56]  
MANZER LE, 1982, INORG SYN, V21, P135
[57]   SITE-DIRECTED MUTAGENESIS OF AZOTOBACTER-VINELANDII FERREDOXIN-I - [FE-S] CLUSTER-DRIVEN PROTEIN REARRANGEMENT [J].
MARTIN, AE ;
BURGESS, BK ;
STOUT, CD ;
CASH, VL ;
DEAN, DR ;
JENSEN, GM ;
STEPHENS, PJ .
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 1990, 87 (02) :598-602
[58]   BAND STRUCTURE AND FERMI SURFACE OF REO3 [J].
MATTHEIS.LF .
PHYSICAL REVIEW, 1969, 181 (03) :987-&
[59]   ON THE DIFFERENCE BETWEEN IRON MOLYBDENUM COFACTOR OF WILD-TYPE AND NIFV MUTANT MOLYBDENUM IRON PROTEINS OF KLEBSIELLA-PNEUMONIAE - ENDOR, EXAFS, AND ELECTRON-PARAMAGNETIC-RES EVIDENCE [J].
MCLEAN, PA ;
TRUE, AE ;
NELSON, MJ ;
CHAPMAN, S ;
GODFREY, MR ;
TEO, BK ;
ORMEJOHNSON, WH ;
HOFFMAN, BM .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (03) :943-945
[60]   EVIDENCE FOR THE FORMATION OF A COFE3S4 CLUSTER IN DESULFOVIBRIO-GIGAS FERREDOXIN-H [J].
MOURA, I ;
MOURA, JJG ;
MUNCK, E ;
PAPAEFTHYMIOU, V ;
LEGALL, J .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1986, 108 (02) :349-351