A SHORT ASYMMETRIC-SYNTHESIS OF (+)-NONACTIC ACID AND (-)-8-EPI-NONACTIC ACID-INDUCED BY A CHIRAL SULFOXIDE GROUP

被引：45

作者：

SOLLADIE, G

DOMINGUEZ, C

机构：

[1] Ecole Européenne des Hautes Etudes des Industries Chimiques, Laboratoire de Stéréochimie, CNRS, 67008-Strasbourg

[2] University Complutense, Madrid

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1994年 / 59卷 / 14期

关键词：

D O I：

10.1021/jo00093a022

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A short enantioselective synthesis of (+)-(2S,3S,6R,8R)-nonactic acid and (-)-(2R,3R,6S,8R)-epi-nonactic acid is described. The key step was the stepwise stereoselective reduction of the triketo sulfoxide B without any protective group on the different carbonyls.

引用

页码：3898 / 3901

页数：4

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