(R)-(-)-(E)-2,6-DIMETHYL-3,7-OCTADIENE-2,6-DIOL 6-O-BETA-D-GLUCOPYRANOSIDE - NATURAL PRECURSOR OF HOTRIENOL FROM LULO FRUIT (SOLANUM-VESTISSIMUM D) PEELINGS

被引：31

作者：

WINTOCH, H

MORALES, A

DUQUE, C

SCHREIER, P

机构：

[1] UNIV WURZBURG,LEHRSTUHL LEBENSMITTELCHEM,HUBLAND,D-97074 WURZBURG,GERMANY

[2] UNIV NACL COLOMBIA,DEPT QUIM,BOGOTA,COLOMBIA

来源：

JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY | 1993年 / 41卷 / 08期

关键词：

D O I：

10.1021/jf00032a028

中图分类号：

S [农业科学];

学科分类号：

09 ;

摘要：

A glycosidic fraction was obtained from a methanolic extract of lulo fruit (Solanum vestissimum D.) peelings by Amberlite XAD-2 adsorption and methanol elution. Using preseparation by rotation locular countercurrent chromatography, subsequent acetylation, and liquid chromatographic purification, a glycoside was isolated in pure form whose structure was elucidated by DCI-MS and NMR analyses to be the 6-O-linked beta-D-glucopyranoside of (R)-(-)-(E)-2,6-dimethyl-3,7-octadiene-2,6-diol.

引用

页码：1311 / 1314

页数：4

共 24 条

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