CHARACTERIZATION OF HYDROXYLATED OXIDE FILM ON IRON SURFACES AND ITS ACID-BASE PROPERTIES USING XPS

被引：43

作者：

KURBATOV, G ^{[1
]}

DARQUECERETTI, E ^{[1
]}

AUCOUTURIER, M ^{[1
]}

机构：

[1] CNRS,PHYS SOLIDE LAB,F-92195 MEUDON,FRANCE

来源：

SURFACE AND INTERFACE ANALYSIS | 1992年 / 18卷 / 12期

关键词：

D O I：

10.1002/sia.740181206

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

X-ray photoelectron spectroscopy was used to characterize the hydroxylated oxide film on iron surfaces. The composition of the films and its transformations for eighteen specimens prepared by ex situ techniques and simulating various conditions of hydroxylated oxide layer formation were examined. A model of hydroxylated oxide multilayer film formation on iron was proposed. Quantitative analysis procedures of its composition and hydroxyl group population determination were given. Anion and cation exchange experiments at the specimen surfaces in solutions at different values of pH followed by x-ray photoelectron analysis of the surface compositions were employed for the estimation of acid-base properties.

引用

页码：811 / 820

页数：10

共 41 条

[31] HARTREE-SLATER SUBSHELL PHOTOIONIZATION CROSS-SECTIONS AT 1254 AND 1487EV [J].

SCOFIELD, JH .

JOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA, 1976, 8 (02) :129-137

[32]

Seah M. P., 1979, Surface and Interface Analysis, V1, P2, DOI 10.1002/sia.740010103

[33] QUANTITATIVE AES AND XPS - DETERMINATION OF THE ELECTRON SPECTROMETER TRANSMISSION FUNCTION AND THE DETECTOR SENSITIVITY ENERGY DEPENDENCIES FOR THE PRODUCTION OF TRUE ELECTRON-EMISSION SPECTRA IN AES AND XPS [J].

SEAH, MP ;

SMITH, GC .

SURFACE AND INTERFACE ANALYSIS, 1990, 15 (12) :751-766

[34] AN ELECTROMETRIC AND ELECTRON DIFFRACTION STUDY OF AIR-FORMED OXIDE FILMS ON IRON [J].

SEWELL, PB ;

STOCKBRIDGE, CD ;

COHEN, M .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1961, 108 (10) :933-941

[35] HIGH-RESOLUTION X-RAY PHOTOEMISSION SPECTRUM OF VALENCE BANDS OF GOLD [J].

SHIRLEY, DA .

PHYSICAL REVIEW B, 1972, 5 (12) :4709-&

[36] CHARACTERIZATION OF ACID-BASE PROPERTIES OF THE HYDRATED OXIDES ON IRON AND TITANIUM METAL-SURFACES [J].

SIMMONS, GW ;

BEARD, BC .

JOURNAL OF PHYSICAL CHEMISTRY, 1987, 91 (05) :1143-1148

[37]

WAGNER CD, 1979, HDB XPS

[38]

WANDELT K, 1982, SURF SCI REP, V2, P63

[39] THE DETERMINATION OF THE ACID-BASE PROPERTIES OF INORGANIC SURFACES BY X-RAY PHOTOELECTRON-SPECTROSCOPY [J].

WATTS, JF ;

GIBSON, EM .

INTERNATIONAL JOURNAL OF ADHESION AND ADHESIVES, 1991, 11 (02) :105-108

[40]

WEAST RC, 1983, HDB CHEM PHYSICS

← 1 2 3 4 5 →