CARBON-CARBON BOND FORMATION WITH NEW MITSUNOBU REAGENTS

被引：65

作者：

TSUNODA, T

NAGAKU, M

NAGINO, C

KAWAMURA, Y

OZAKI, F

HIOKI, H

ITO, S

机构：

[1] Faculty of Pharmaceutical Sciences, Tokushima Bunri University, Tokushima

来源：

TETRAHEDRON LETTERS | 1995年 / 36卷 / 14期

关键词：

D O I：

10.1016/0040-4039(95)00300-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The efficiency of three azodicarboxylic acid derivatives and a stabilized phosphorane in the Mitsunobu type C-C bond formation was compared utilizing the reactions of three nucleophiles of different pK(a)'s and several alcohols of different structure types. The study established the characteristics of each reagent. The synthesis of two insect pheromone analogs was accomplished effectively using these homologation reactions.

引用

页码：2531 / 2534

页数：4

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