Kesterite thin films for photovoltaics: a review

被引：180

作者：

Delbos, S. ^{[1
,2
,3
]}

机构：

[1] IRDEP, EDF R&D, 6 Quai Watier, F-78401 Chatou, France

[2] CNRS, UMR 7174, F-78401 Chatou, France

[3] Chim ParisTech, F-75005 Paris, France

来源：

EPJ PHOTOVOLTAICS | 2012年 / 3卷

关键词：

D O I：

10.1051/epjpv/2012008

中图分类号：

O59 [应用物理学];

学科分类号：

摘要：

In the years to come, electricity production is bound to increase, and Cu2ZnSn(S, Se) 4 (CZTS) compounds, due to their suitability to thin-film solar cells, could be a means to fulfill the demand. After explaining the reasons of the sudden interest of the CIGS scientific community for CZTS solar cells, this paper reviews recent papers published on the subject of kesterites-based solar cells. After a description of crystallographic and optoelectronic properties, including CZTS crystalline structure, defect formation and metal composition, this review paper focuses on CZTS synthesis processes and device properties. Synthesis strategies, including one-or two-step processes, deposition temperature, binary formation control via atmosphere control and their effect on device properties are discussed.

引用

页数：13

共 169 条

[11]

Bar M., J MAT RES FIRSTVIEW, V1

[12] Device characteristics of a 10.1% hydrazine-processed Cu2ZnSn(Se,S)4 solar cell [J].

Barkhouse, D. Aaron R. ;

Gunawan, Oki ;

Gokmen, Tayfun ;

Todorov, Teodor K. ;

Mitzi, David B. .

PROGRESS IN PHOTOVOLTAICS, 2012, 20 (01) :6-11

[13] Fabrication of Cu2ZnSnS4 solar cells by sulfurization of evaporated precursors [J].

Biccari, Francesco ;

Chierchia, Rosa ;

Valentini, Matteo ;

Mangiapane, Pietro ;

Salza, Enrico ;

Malerba, Claudia ;

Ricardo, Cristy Leonor Azanza ;

Mannarino, Loredana ;

Scardi, Paolo ;

Mittiga, Alberto .

EUROPEAN MATERIALS RESEARCH SOCIETY CONFERENCE SYMPOSIUM: ADVANCED INORGANIC MATERIALS AND CONCEPTS FOR PHOTOVOLTAICS, 2011, 10 :187-191

[14] A model for the mechanism of incorporation of Cu, Fe and Zn in the stannite -: Kesterite series, Cu2FeSnS4-Cu2ZnSnS4 [J].

Bonazzi, P ;

Bindi, L ;

Bernardini, GP ;

Menchetti, S .

CANADIAN MINERALOGIST, 2003, 41 :639-647

[15]

Breyer C., 2011, 26 S PHOT SOL BAD ST

[16]

Brockway LO, 1934, Z KRISTALLOGR, V89, P434

[17] Fabrication of Cu2ZnSnS4 films by sulfurization of Cu/ZnSn/Cu precursor layers in sulfur atmosphere for solar cells [J].

Chalapathy, R. B. V. ;

Jung, Gwang Sun ;

Ahn, Byung Tae .

SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2011, 95 (12) :3216-3221

[18] Preparation of Cu2ZnSnS4 films by electrodeposition using ionic liquids [J].

Chan, C. P. ;

Lam, H. ;

Surya, C. .

SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2010, 94 (02) :207-211

[19] Earth-abundant non-toxic Cu2ZnSnS4 thin films by direct liquid coating from metal-thiourea precursor solution [J].

Chaudhuri, Tapas Kumar ;

Tiwari, Devendra .

SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2012, 101 :46-50

[20] INEXPENSIVE, ABUNDANT, NON-TOXIC THIN FILMS FOR SOLAR CELL APPLICATIONS GROWN BY REACTIVE SPUTTERING [J].

Chawla, Vardaan ;

Clemens, Bruce .

35TH IEEE PHOTOVOLTAIC SPECIALISTS CONFERENCE, 2010, :1902-1905

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