AXIALLY DISSYMMETRIC DIPHOSPHINES IN THE BIPHENYL SERIES - CRYSTAL-STRUCTURES OF 3 NEW GROUP-VIII METAL-COMPLEXES OF (6,6'-DIMETHYL-1,1'-BIPHENYL-2,2'-DIYL)BIS(DIPHENYLPHOSPHINE) (= BIPHEMP)

被引：28

作者：

KNIERZINGER, A ^{[1
]}

SCHONHOLZER, P ^{[1
]}

机构：

[1] F HOFFMANN LA ROCHE & CO LTD,CENT RES UNIT,CH-4002 BASEL,SWITZERLAND

来源：

HELVETICA CHIMICA ACTA | 1992年 / 75卷 / 04期

关键词：

D O I：

10.1002/hlca.19920750421

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(6,6'-Dimethyl-1,1'-biphenyl-2,2'-diyl)bis(diphenylphosphine) ( = biphemp) reacts with allylmetal halides to yield complexes 1-3 which were transformed into the corresponding perchlorates 4-6. The molecular structures of 4-6 were determined by X-ray analyses.

引用

页码：1211 / 1220

页数：10

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