AN IMPROVED SYNTHESIS OF RU(BINAP) TYPE COMPLEXES

被引：10

作者：

CHAN, ASC

LANEMAN, S

机构：

[1] HONG KONG UNIV SCI TECHNOL,DEPT CHEM,HONG KONG,HONG KONG

[2] HONG KONG POLYTECH,DEPT APPL BIOL & CHEM TECHNOL,HONG KONG,HONG KONG

[3] SEARLE RES & DEV,SKOKIE,IL

来源：

INORGANICA CHIMICA ACTA | 1994年 / 223卷 / 1-2期

关键词：

RUTHENIUM COMPLEXES; BINAP COMPLEXES;

D O I：

10.1016/0020-1693(94)03986-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

New synthetic methods for the preparation of Ru(BINAP) complexes have been developed. A major decomposition product, diphenylphosphinyl[1-(1'-naphthyl)-2-naphthyl)diphenylphosphine]ruthenium chloride, was identified and a simple, high yield synthesis of Ru(BINAP)(OAc)2 was developed based on the understanding of this byproduct.

引用

收藏

页码：165 / 167

页数：3

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