NEW TERPENOID HOSTS FOR CHIRAL RECOGNITION - CRYSTAL-STRUCTURE AND MOLECULAR MODELING STUDY OF AN INCLUSION COMPLEX WITH (S)-(+)-PHENYLOXIRANE

被引：29

作者：

KORKAS, PP

WEBER, E

CZUGLER, M

NARAYSZABO, G

机构：

[1] HUNGARIAN ACAD SCI, CENT RES INST CHEM, H-1525 BUDAPEST, HUNGARY

[2] TECH UNIV BERGAKAD FREIBERG, INST ORGAN CHEM, D-09596 FREIBURG, GERMANY

[3] EOTVOS LORAND UNIV, DEPT THEORET CHEM, H-1518 BUDAPEST, HUNGARY

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 21期

关键词：

D O I：

10.1039/C39950002229

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new type of optically active inclusion host derived from natural camphor is described, enabling useful enantiomer separation of chiral compounds via cocrystallization; the structural rationale of an inclusion complex with (S)-(+)-phenyloxirane based on X-ray determination and a molecular modelling study is reported.

引用

页码：2229 / 2230

页数：2

共 17 条

[1]

[Anonymous], 1995, STEREOSELECTIVE SYNT

[2]

[Anonymous], 1982, ACS MONOGRAPH

[3]

BRITTELLI R, 1981, J ORG CHEM, V46, P312

[4] MACROCYCLIC ACETYLENIC COMPOUNDS .1. CYCLOTETRADECA-1,3-DIYNE AND RELATED COMPOUNDS [J].