RHODIUM-CATALYZED REACTION OF BENZOIC ANHYDRIDE WITH STYRENE UNDER MOLECULAR-HYDROGEN

被引：64

作者：

KOKUBO, K ^{[1
]}

MIURA, M ^{[1
]}

NOMURA, M ^{[1
]}

机构：

[1] OSAKA UNIV,FAC ENGN,DEPT APPL CHEM,SUITA,OSAKA 565,JAPAN

来源：

ORGANOMETALLICS | 1995年 / 14卷 / 10期

关键词：

D O I：

10.1021/om00010a016

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

It has been found that styrene undergoes intermolecular hydrobenzoylation by benzoic anhydride under a normal pressure of molecular hydrogen in the presence of a tertiary amine and a catalytic amount of [RhCl(cod)](2) and a phosphorous ligand to give a mixture of 1,2- and 1,3-diphenyl-1-propanones. The catalyst efficiency has been observed to be a marked function of the ligand employed; triphenylphosphite appears to be one of the favorable ones. The reaction using deuterium has also been carried out to obtain insight into the reaction mechanism.

引用

页码：4521 / 4524

页数：4

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