INTRAMOLECULAR CYCLOPROPANATION REACTIONS OF CHROMIUM (ALKENYLOXY)CARBENE COMPLEXES

被引：66

作者：

SODERBERG, BC ^{[1
]}

HEGEDUS, LS ^{[1
]}

机构：

[1] COLORADO STATE UNIV, DEPT CHEM, FT COLLINS, CO 80523 USA

来源：

ORGANOMETALLICS | 1990年 / 9卷 / 12期

关键词：

D O I：

10.1021/om00162a024

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Chromium (aryl)(alkenyloxy)carbene complexes underwent intramolecular cyclopropanation reactions under mild conditions. Evidence for the intervention of metathesis/readdition and for “twist” addition followed by β-hydride elimination/reductive elimination was obtained. Carbenes of this class, sufficiently stable to isolate, underwent facile photochemical intramolecular cyclobutanone formation. © 1990, American Chemical Society. All rights reserved.

引用

页码：3113 / 3121

页数：9