REACTION BETWEEN CH3 AND NO AT COMBUSTION TEMPERATURES

被引:15
作者
YANG, H
LISSIANSKI, V
OKOROANYANWU, JU
GARDINER, WC
SHIN, KS
机构
[1] UNIV TEXAS, DEPT CHEM & BIOCHEM, AUSTIN, TX 78712 USA
[2] SOONG SIL UNIV, DEPT CHEM, SEOUL 156743, SOUTH KOREA
关键词
D O I
10.1021/j100141a024
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The reaction between CH3 radicals and NO was investigated behind incident shock waves at temperatures between 1370 and 2500 K and densities near 3 mol/m3 by following the consumption of CH3 with time-resolved UV absorption measurements at 213.9 nm. The rate coefficient expression 1.2 x 10(14) exp(-14500 K/T) cm3 mol-1 s-1 for the total reaction of CH3 with NO was derived.
引用
收藏
页码:10042 / 10046
页数:5
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