REACTION BETWEEN CH3 AND NO AT COMBUSTION TEMPERATURES

被引：15

作者：

YANG, H

LISSIANSKI, V

OKOROANYANWU, JU

GARDINER, WC

SHIN, KS

机构：

[1] UNIV TEXAS, DEPT CHEM & BIOCHEM, AUSTIN, TX 78712 USA

[2] SOONG SIL UNIV, DEPT CHEM, SEOUL 156743, SOUTH KOREA

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1993年 / 97卷 / 39期

关键词：

D O I：

10.1021/j100141a024

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The reaction between CH3 radicals and NO was investigated behind incident shock waves at temperatures between 1370 and 2500 K and densities near 3 mol/m3 by following the consumption of CH3 with time-resolved UV absorption measurements at 213.9 nm. The rate coefficient expression 1.2 x 10(14) exp(-14500 K/T) cm3 mol-1 s-1 for the total reaction of CH3 with NO was derived.

引用

页码：10042 / 10046

页数：5

共 44 条

[11] OPTIMIZATION AND ANALYSIS OF LARGE CHEMICAL KINETIC MECHANISMS USING THE SOLUTION MAPPING METHOD - COMBUSTION OF METHANE [J].