(CYCLOPENTADIENYL)-GALLIUM(I)-COMPOUNDS

被引：70

作者：

LOOS, D ^{[1
]}

SCHNOCKEL, H ^{[1
]}

机构：

[1] UNIV MUNICH,INST ANORGAN CHEM,W-8000 MUNICH 2,GERMANY

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1993年 / 463卷 / 1-2期

关键词：

D O I：

10.1016/0022-328X(93)83395-C

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A metastable solution of GaCl reacts with LiCp or MgCp(2) compounds to a number of new cyclopentadienylgallium(I) species: GaCp*, GaCp(tBu), GaCp((SiMe3)3) and GaCp((Benzyl)5). They are characterized by their mass and NMR spectra (H-1, C-13 and Ga-71). By comparison with analogous Al and Mg compounds eta(5)-bonding has to be concluded for air GaCp derivatives.

引用

页码：37 / 40

页数：4

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